Sodium silver tricobalt bis(diphosphate) and sodium silver copper(II) diphosphate
Identifieur interne : 000A91 ( Main/Exploration ); précédent : 000A90; suivant : 000A92Sodium silver tricobalt bis(diphosphate) and sodium silver copper(II) diphosphate
Auteurs : J. Bennazha ; Ali Boukhari ; Elizabeth M. HoltSource :
- Acta Crystallographica Section C [ 0108-2701 ] ; 2002-07.
Descripteurs français
- Pascal (Inist)
- (Na1,12Ag0,88)CuP2O7, (Na1,42Ag0,58)Co3(P2O7)2, 6166F, Ag Co Na O P, Ag Cu Na O P, Argent Diphosphate, Argent cobalt sodium diphosphate mixte, Argent cuivre sodium diphosphate mixte, Cobalt Diphosphate, Cuivre Diphosphate, Diffraction RX, Distribution ion, Etude expérimentale, Occupation site, Phosphate, Sodium Diphosphate, Structure cristalline, Substitution ion.
- Wicri :
- topic : Phosphate.
English descriptors
- KwdEn :
Abstract
The crystal structures of two new diphosphates, sodium silver tricobalt bis(diphosphate), (Na1.42Ag0.58)Co3(P2O7)2, and sodium silver copper(II) diphosphate, (Na1.12Ag0.88)CuP2O7, provide examples of the effect of mixing Na and Ag in the same site of known host phosphate compounds. The small differences in ionic radii of the two monocations do not lead to significant differences in the structural details. In the latter compound, the Cu atom lies on an inversion center.
Url:
DOI: 10.1107/S0108270102008922
Affiliations:
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Le document en format XML
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